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Edvin Lundgren. Portrait.

Edvin Lundgren

Professor

Edvin Lundgren. Portrait.

The Pd(100)-(root 5 x root 5)R27 degrees-O surface oxide revisited

Author

  • M Todorova
  • Edvin Lundgren
  • V Blum
  • Anders Mikkelsen
  • Struan Gray
  • Johan Gustafson
  • Mikael Borg
  • J Rogal
  • K Reuter
  • Jesper N Andersen
  • M Scheffler

Summary, in English

Combining high-resolution core-level spectroscopy, scanning tunneling microscopy and density-functional theory calculations we reanalyze the Pd(100)-(root5 x root5)R27degrees-O surface oxide phase. We find that the prevalent structural model, a rumpled PdO(001) film suggested by previous low energy electron diffraction (LEED) work [Surf. Sci. 494 (2001) L799], is incompatible with all three employed methods. Instead, we suggest the two-dimensional film to consist of a strained PdO(101) layer on top of Pd(100). LEED intensity calculations show that this model is compatible with the experimental data of Saidy et al. (C) 2003 Elsevier B.V. All rights reserved.

Department/s

  • Synchrotron Radiation Research
  • Department of Physics

Publishing year

2003

Language

English

Pages

101-112

Publication/Series

Surface Science

Volume

541

Issue

1-3

Document type

Journal article

Publisher

Elsevier

Topic

  • Atom and Molecular Physics and Optics

Keywords

  • low energy electron diffraction (LEED)
  • photoelectron spectroscopy
  • scanning tunneling microscopy
  • photoemission (total yield)
  • oxygen
  • palladium
  • density functional calculations

Status

Published

ISBN/ISSN/Other

  • ISSN: 0039-6028