
Anders Mikkelsen
Professor

High-coverage oxygen structures on Rh(111): Adsorbate repulsion and site preference is not enough
Author
Summary, in English
A new O induced structure on Rh(111) displaying a (2root3 x 2root3)R30degrees periodicity with an oxygen coverage of 2/3 has been studied by high resolution core level spectroscopy, scanning tunneling microscopy, and density functional theory. Although O favors fcc hollow sites in all other known phases, it occupies both fcc and hcp sites in this structure, which cannot be explained by pairwise adsorbate repulsion only. Both the (22root3 x 2root3)R30degrees and (2x2)-3O structures also exemplify that density-of-states contrast can lead to oxygen adatoms appearing as protrusions in scanning tunneling microscopy images.
Department/s
- Synchrotron Radiation Research
Publishing year
2004
Language
English
Publication/Series
Physical Review Letters
Volume
93
Issue
26
Document type
Journal article
Publisher
American Physical Society
Topic
- Atom and Molecular Physics and Optics
Status
Published
ISBN/ISSN/Other
- ISSN: 1079-7114